Product ID:SOLUTION SH355 P-1
MSDS Date:06/27/1989
FSC:6850
NIIN:00N047706
MSDS Number: BSTLM

NALCO CHEMICAL COMANY

ONE NALCO CENTER
NAPERVILLE, IL 60563-1198
US

Emergency Phone: 708-920-1510(24 HOURS)

Info Phone: 708-305-1000

Preparer: RICKY A. STACKHOUSE

Cage: 89524

ONDEO NALCO COMPANY

NAPERVILLE, IL 60563-1198 US

Telephone: (630) 305-1000

Cage: 89524

ACID SOLN MAY BE DISPOSED INTO WASTE

RTECS: 9999999ZZ

PRODUCT CONTAINER SHOULD BE PUNCTURED, IF PLASTIC &

RTECS: 9999999ZZ

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 30%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MOLYBDIC ACID, DIAMMONIUM SALT; (AMMONIUM MOLYBDATE)

CAS: 13106-76-8

RTECS: QA4900000

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: N/K

CNDTN. PROBABLE MUCOSAL DMG MAY CONTRAINDICATE USE

RTECS: 9999999ZZ

RESPIRATORY DEPRESSION & CONVULSIONS MAY BE NEEDED.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE:CORROSIVE W/POSSIBLE PERMANENT
DAMAGE DEPENDING ON LENGTH OF EXPOSURE & ON FIRST AID ACTION GIVEN.
SKIN:CORROSIVE, POSSIBLY RESULTING IN THIRD DEGREE BURNS DEPENDING
ON LENGTH OF EXPOSURE & ON FIR ST AID ACTION GIVEN. INGEST:CAN BE
HARMFUL. INHAL:CAN BE CORROSIVE TO MUCOUS MEMBRANES & LUNGS.
Explanation of Carcinogenicity:SULFURIC ACID:IARC MONOGRAPHS ON
EVALUATION OF CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 41, 1992:GRP
1.
Effects of Overexposure:A REVIEW OF AVAILABLE DATA DOES NOT INDENTIFY
ANY SYMPTOMS FROM EXPOSURE.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.

First Aid:EYES:IMMED FLUSH FOR AT LST 15 MINS WHILE HOLDING EYELIDS
OPEN. CALL MD AT ONCE. SKIN:IMMED FLUSH W/WATER FOR AT LST 15 MINS.
FOR LG SPLASH, FLOOD BODY UNDER SHOWER. CALL MD AT ONCE. INGEST:DO
NOT IND UCE VOMIT. GIVE WATER. CALL MD. CAUTION:IF UNCON, HAVING
TROUBLE BRTHG/IN CONVLS, DO NOT INDUCE VOMIT/GIVE WATER.
INHAL:REMOVE TO FRESH AIR. TREAT SYMPS. CALL MD. NOTE TO MD:NO
SPECIFIC (SUPP DATA)

Flash Point:NONE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY EVOLVE SO*X UNDER FIRE CONDITIONS.

Spill Release Procedures:COVER SPILL W/SODIUM BICARBONATE. MIX & ADD
WATER TO FORM A SLURRY. SCOOP UP & DISPOSE THROUGH WASTE TREATMENT
SYSTEM. THIS PROD CNTNS SULFURIC ACID, RQ SUBSTANCE & IF 3,000 LBS
OF PROD ARE RELS, IT R EQS NOTIFICATION TO NRC (1-800-424-8802).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE SMOKE OR FUMES.
CORROSIVE CAUSES BURNS TO SKIN & EYES. DO NOT GET IN EYES, ON SKIN
OR ON CLOTHING. DO NOT TAKE INTERNALLY.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:IF IT IS POSSIBLE TO GENERATE SUFFICIENT LEVELS
OF VAPORS OR MISTS, A NIOSH/MSHA APPROVED OR EQUIVALENT ACID
RESPIRATOR IS RECOMMENDED.
Ventilation:GENERAL VENT IS RECOMMENDED. ADDITIONALLY, LOCAL EXHAUST
VENTILATION IS REC WHERE MISTS/AEROSOLS MAY BE RELEASED.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL SPLASH GOGGLES & FACE SHIELD.
Other Protective Equipment:WEAR SUITABLE PROTECTIVE EQUIPMENT, APRON.
AVAILABILITY OF EYE WASH FOUNTAIN & SAFETY SHOWER IS RECOMMENDED.
Work Hygienic Practices:IF CLOTHING IS CONTAMINATED, REMOVE CLOTHING &
THORO WASH AFFECTED AREA. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
PH:<1(NEAT). MATLS TO AVOID:HYDROXIDE, CALCIUM HYDROXIDE (LIME),
CYANIDES, SULFIDES, HYPOCHLORITES, CHLORITES) WHICH CAN GENERATE
HEAT W/SPLATTERING OR BOILING & RELS OF TOX FUMES. FIRST AID
PROC:ANTI DOTE IS KNOWN. BASED ON INDIVIDUAL RXNSOF PATIENT, MD'S
JUDGMENT SHOULD BE USED TO CONTROL SYMPS & CLINICAL (ING 3)

HCC:C1
pH:SUPDAT
Solubility in Water:COMPLETELY
Appearance and Odor:CLEAR LIQUID.

Stability Indicator/Materials to Avoid:YES
AVOID ORG MATLS. AVOID ALKALINE MATLS (E.G. AMMONIA & ITS SOLNS,
CARBONATES, SODIUM HYROXIDE(CAUSTIC), POTASSIUM(SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN THE EVENT OF COMBUSTION NO*X, SO*X
MAY BE FORMED.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . IF
THIS PROD BECOMES A WASTE, IT MEETS CRITERIA OF HAZ WASTE AS
DEFINED UNDER RCRA 40 CFR 261. HAZ WASTE D002. ACID SOLNS SHOULD BE
NEUT BEFORE BEING D ISCHARGED TO SANIT SEWER. ALTERNATIVELY, (ING
5)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.